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Answers toStudent Questions

Chemistry

Why does electronegativity increase across and up the periodic table?

Electronegativity increases across a period (left to right) and up a group because of the combined effects of atomic size and effective nuclear charge. Electronegativity is the ability of an atom to attract the shared pair of electrons in a covalent bond. As you move across a period, the number of protons increases while electrons are being added to the same shell, resulting in a higher effective nuclear charge, which is the net positive charge experienced by valence electrons after accounting for shielding. Since the shielding remains relatively constant across a period (same number of inner shells), the increased nuclear charge pulls the valence electrons more tightly, making the atom smaller and better able to attract bonding electrons. This is why fluorine, at the far right of Period 2, is more electronegative than carbon or nitrogen in the same period. Moving up a group, electronegativity increases primarily due to decreasing atomic size. As you go up a group, there are fewer electron shells between the nucleus and the bonding electrons. For example, fluorine (Period 2) has only two electron shells while iodine (Period 5) has five. When atoms form covalent bonds, the shared electrons in smaller atoms are much closer to the nucleus and experience a stronger electrostatic attraction, despite the smaller number of protons. The effect of decreasing distance outweighs the effect of decreasing nuclear charge as you move up a group. These two trends combine to make fluorine, located in the upper right of the periodic table, the most electronegative element with a value of 4.0, while francium in the lower left would be the least electronegative. The only exception to the trend is the noble gases, which typically don't form bonds and therefore don't have standard electronegativity values.

Economics

What are non-price determinants in economics?

In microeconomics, the price of a product has the most significant effect on consumer behaviour (demand) and producer behaviour (supply). However, many other factors affect the quantities demanded and supplied at every price. For example, consumers will pay a higher price for products they prefer. Hence, if consumer preference for a product increases, consumers will demand more at each price. The demand schedule below shows consumer preferences before and after an advertising campaign. Assuming the advertising campaign is successful—it increases consumer preference for the good—quantity demanded increases at every price. |Price |Quantity demanded$_1$|Quantity demanded$_2$| |:-:|:-:|:-:| |$0|200|250| |$10|150|200| |$20|100|150| |$30|50|100| |$40|0|50| Economists call this change an increase in demand. An increase in demand differs from an increase in *quantity demanded*, which occurs when the price decreases. An increase in demand is shown by a rightward shift of the demand curve; a decrease in demand is shown by a leftward shift of the demand curve. The table below shows how the determinants and how they impact demand: |Non-price determinant of demand|Demand shifts right if…|Demand shifts left if…| |:-:|:-:|:-:| |Tastes and preferences|consumers want a product more|consumers want a product less| |Price of related goods (substitutes)|price of other goods increases|price of other goods decreases| |Price of related goods (complements)|price of other goods decreases|price of other goods increases| |Income (normal goods)|incomes increase|incomes decrease| |Income (inferior goods)|incomes decrease|incomes increase| |Future expectations of price|prices are expected to rise|prices are expected to fall| |Number of consumers|consumers join market|consumers leave market| Similarly, when factors other than price change producer preference, supply increases (the supply curve shifts right) or decreases (the supply curve shifts left). |Non-price determinant of supply |Supply shifts right if…|Supply shifts left if…| |:-:|:-:|:-:| |Cost of raw materials/labour|costs decrease|costs increase| |Price of related goods (joint supply)|price of other goods increases|price of other goods decreases| |Price of related goods (competitive supply)|price of other goods decreases|price of other goods increases| |Taxes and subsidies|indirect taxes decrease/subsidies increase|indirect taxes increase/subsidies decrease| |Future expectations of price|prices are expected to fall|prices are expected to rise| |Technology|technology increases|technology decreases| |Number of firms|firms join market|firms leave market|

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